PA Classical languages (Latin and
Greek)
PB Celtic
PC Romance
languages
PD Germanic languages
PE English language
PG Slavic
languages
PH Finno-Ugric
PJ Arabic,
Hebrew, Semitic, East Asian
PK Indo-Iranian
languages and literatures
PL Turkic, and Asian
languages
PM Native American languages
For the fuller (but not totally complete) Library of Congress schedule for language families and languages, please follow this link (a Google shared pdf document, so links don't work) or download the original pdf at Library of Congress.